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ASTM A335 P91 Alloy Steel Seamless Pipe

ASTM A335 P91 Alloy Steel Seamless Pipe

High-temperature & Corrosion-resistant

Astm a335 p91 alloy steel seamless pipe offers exceptional creep strength and corrosion resistance, ideal for boiler pipeline protection in power plants and petrochemical industries.

ASTM A335 P91 Alloy Steel Seamless Pipe

High-temperature & Corrosion-resistant

Astm a335 p91 alloy steel seamless pipe offers exceptional creep strength and corrosion resistance, ideal for boiler pipeline protection in power plants and petrochemical industries.

ASTM A335 P91 Pipe is a seamless ferritic alloy steel pipe engineered for high-temperature and high-pressure service, offering outstanding corrosion resistance and creep resistance. Conforming to the ASTM A335/ASME SA335 specification and designated as UNS K91560, this Chrome Moly Pipe is crafted with a composition of 8.00-9.50% chromium, 0.85-1.05% molybdenum, and enhanced with vanadium, niobium, and nitrogen, making it a creep strength enhanced ferritic (CSEF) steel. It is ideal for boiler pipeline protection in supercritical and ultra-supercritical power plants, petrochemical industries, and other industrial piping systems requiring durability under extreme conditions.

The ASTM A335 P91 Pipe is manufactured through hot-rolling or cold-drawing processes, followed by specific heat treatment: normalizing at 1040-1080°C and tempering at 730-800°C to achieve a martensitic microstructure with superior mechanical properties. The addition of vanadium (0.18-0.25%), niobium (0.06-0.10%), and nitrogen (0.03-0.07%) enhances creep strength and high-temperature performance, making it suitable for applications up to 650°C. The pipe is designed for bending, flanging, and fusion welding, requiring preheating (200°C) and post-weld heat treatment (PWHT at 730-760°C) to prevent cracking, especially for thicker walls. Available in sizes from 1/2” to 24” (DN15 to DN600), with wall thicknesses from SCH 40 to SCH XXS, and lengths up to 16 meters, it meets diverse project requirements.

The Seamless Alloy Pipes undergo rigorous testing, including tensile, flattening, hardness, and hydrostatic tests, to ensure compliance with ASTM A335 standards. With a minimum tensile strength of 585 MPa, yield strength of 415 MPa, and elongation of 20%, the pipe offers robust resistance to high temperatures and pressures. Its corrosion resistance is enhanced by high chromium content, making it ideal for handling corrosive fluids and gases in petrochemical applications, while its creep resistance supports long-term performance in high-pressure steam lines. Surface treatments like oil-dip, varnish, or 3LPE/FBE coatings enhance durability, and plain or beveled ends facilitate easy installation.

Compared to grades like P22 or P11, the ASTM A335 P91 Pipe is optimized for supercritical and ultra-supercritical boiler systems due to its superior creep strength, allowing for thinner walls and improved thermal efficiency. Its resistance to hydrogen sulfide corrosion and stress cracking makes it suitable for oil and gas pipelines, while its robustness supports applications in reheat lines, heat exchangers, and high-pressure boiler components. The pipe’s compatibility with ASTM A234 WP91 fittings ensures seamless integration into complex piping systems, making it a preferred choice for engineers seeking reliable industrial piping solutions.

Chemical Composition & Mechanical Properties

Chemical Composition of ASTM A335 P91
Element Composition (%)
Carbon (C) 0.08–0.12
Manganese (Mn) 0.30–0.60
Phosphorus (P) ≤0.02
Sulfur (S) ≤0.01
Silicon (Si) 0.20–0.50
Chromium (Cr) 8.00–9.50
Molybdenum (Mo) 0.85–1.05
Vanadium (V) 0.18–0.25
Niobium (Nb) 0.06–0.10
Nitrogen (N) 0.03–0.07
Mechanical Properties of ASTM A335 P91
Property Value
Tensile Strength (MPa) 585 min
Yield Strength (MPa) 415 min
Elongation (%) 20 min
Hardness (HBW) ≤250
ASTM A335 P91 Type1 VS Type2
Grade UNS Designation Chemical Composition %
P91 Type 1 K91560 C Mn P S Si Ni Cr Mo
0.08-0.12 0.30-0.60 0.020 0.010 0.20-0.50 0.40 max 8.00-9.50 0.85-1.05
V N Al Cb Ti Zr Sn Sb
0.18-0.25 0.030-0.070 0.02 max 0.06-010 0.01 max 0.01 max _ _
P91 Type 2 K91560 C Mn P S Si Ni Cr Mo
0.08-0.12 0.30-0.50 0.020 0.005 0.20-0.40 0.40 max 8.00-9.50 0.85-1.05
V N Al Cb Ti Zr Sn Sb
0.18-0.25 0.035-0.070 0.02 max 0.06-0.10 0.01 max 0.01 max 0.010 max 0.003 max

ASTM A335 P91 Type 1 & Type 2 have subtle differences mainly in elements Mn, S, Si, N, Sn and Sb content, and Type 2 has stricter requirements on element content than Type 1. P91 type 1 and 2 shall have a hardness within the range of 190 to 250 [HBW] or 196 to 265 [HV] or 91 HRBW to 25 HRC.

Advantages of ASTM A335 P91 Alloy Steel

P91 (9Cr-1Mo-V-Nb) is a high-performance ferritic alloy steel designed for high-temperature service in power plants and petrochemical systems.

High Temperature Strength

Maintains mechanical performance up to 600°C, allowing reduced wall thickness in steam piping and headers.

Oxidation Resistance

Withstands aggressive thermal and chemical environments, supporting advanced boiler design.

Thermal Fatigue Life

Offers up to 10× longer fatigue life compared to conventional steels, reducing shutdowns and failures.

Microstructure Stability

Requires controlled heat treatment to maintain tempered martensitic structure and creep strength.

Alloy Composition

Chromium, molybdenum, vanadium, and niobium enhance strength, oxidation resistance, and weldability.

Weldability & Applications

Widely used in superheaters, reheaters, HRSGs, and headers with compatible welding consumables.

P91 alloy steel has become the industry standard for high-efficiency power plant systems. It delivers exceptional performance in demanding thermal environments and is essential for systems operating under high pressure and temperature conditions.

FAQ

ASTM A335 P91 is a seamless ferritic chrome moly alloy steel pipe used for high-temperature and anti-corrosion services. It contains 8.00–9.50% chromium and 0.85–1.05% molybdenum, with a minimum tensile strength of 415 MPa and yield strength of 205 MPa. It is commonly used in power plants, chemical plants, and other industrial facilities due to its excellent high-temperature strength and resistance to oxidation and corrosion.

ASTM A335/ASME SA335 Grade P91 is a ferritic alloy steel known for its high creep strength and resistance to thermal fatigue. Also referred to as 9Cr-1Mo steel, it is used in high-pressure, high-temperature environments such as boiler tubes, superheaters, and heat exchangers.

P91 Type 1 and Type 2 differ in chemical composition tolerances. Type 2 has stricter limits on elements like Mn, S, Si, N, Sn, and Sb. Both types share the same hardness range (190–250 HBW or 91 HRBW to 25 HRC) but are selected based on specific performance requirements.

P91 is a creep-strength-enhanced ferritic (CSEF) alloy steel made of 9% chromium and 1% molybdenum. It is designed to retain mechanical strength and stability at elevated temperatures, commonly used in high-temperature piping systems.

P91 (UNS K91560) is equivalent to the national standard 10Cr9Mo1VNb. It is a tempered martensitic heat-resistant steel containing elements like chromium, molybdenum, vanadium, and niobium, ensuring excellent thermal and mechanical performance.

P9 is a 9Cr-1Mo alloy steel suited for high-temperature service, while P91 includes additional elements like vanadium, niobium, and nitrogen to enhance creep resistance. P91 offers superior long-term performance under sustained high-temperature and pressure conditions.

P91 and T91 are essentially the same material. "P91" refers to seamless pipe under ASTM A335, while "T91" refers to tubing under ASTM A213. The difference lies in product form and specification, not the material itself.

P91 pipes come in various schedules and wall thicknesses ranging from 3 mm to 12 mm or more, depending on pipe diameter and pressure class. Custom thicknesses are also available to suit specific application requirements.

Industrial Applications

ASTM A335 chrome moly pipes are widely used in various industries due to their excellent mechanical properties and resistance to high temperatures.

Power Generation

Used in high-temperature and high-pressure boiler tubes, superheaters, and reheaters for efficient energy conversion.

Oil & Gas

Applied in refineries and petrochemical plants to transport high-temperature hydrocarbons.

Chemical Processing

Used in facilities handling corrosive and high-temperature fluids during various chemical reactions.

Nuclear Power

Employed in nuclear power plants for critical piping systems resistant to extreme heat and pressure.

Industrial Heating

Used in furnaces and heat exchangers due to excellent resistance to high temperature and thermal fatigue.

Steam Systems

Applied in high-pressure steam systems in industries like pulp and paper where thermal durability is essential.

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