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ASTM A335 P91 Chrome Moly Alloy Pipe

ASTM A335 P91 Chrome Moly Alloy Pipe

High-temperature Boiler Systems

Astm a335 p91 chrome moly pipe delivers exceptional high-temperature strength, corrosion resistance, and durability for critical boiler and heat exchanger systems.

ASTM A335 P91 Chrome Moly Alloy Pipe

High-temperature Boiler Systems

Astm a335 p91 chrome moly pipe delivers exceptional high-temperature strength, corrosion resistance, and durability for critical boiler and heat exchanger systems.

ASTM A335 P91 Alloy Steel Pipe is a seamless ferritic alloy steel pipe formulated for elevated temperature and pressure applications. Also known as Chrome Moly Pipe, it contains approximately 9% chromium and 1% molybdenum with additions of vanadium and niobium to improve strength, oxidation resistance, and structural stability under long-term service.

The P91 pipe is widely used in thermal power plants, superheaters, reheaters, and header lines operating in temperatures ranging from 540°C to 610°C. Its creep rupture strength far surpasses that of earlier grades like P11 and P22, making it the industry standard for ultra-efficient steam systems.

This pipe is manufactured through hot working followed by normalizing and tempering heat treatment to achieve the required mechanical properties. All pipes are subjected to rigorous testing including hydrostatic, hardness, tensile, and ultrasonic inspection to ensure safe operation under extreme service conditions.

Compatible with ASTM A234 WP91 pipe fittings and ASTM A182 F91 flanges, P91 alloy steel ensures complete system consistency in terms of chemical composition, thermal expansion, and pressure rating.

Whether installed in power generation units, refineries, or industrial boilers, ASTM A335 P91 Chrome Moly Pipe offers long-lasting protection against high-temperature corrosion, hydrogen attack, and mechanical fatigue, significantly extending service life and lowering total maintenance costs.

Key Benefits

Excellent High-Temperature Strength

Withstands service conditions up to 610°C without creep rupture failure.

Superior Oxidation Resistance

Chromium content protects against corrosion and scale formation in steam environments.

Compatible With WP91 Fittings

Ensures structural consistency in elbows, tees, reducers, and flanges.

Extended Life Cycle

Minimizes failure due to fatigue, thermal stress, and material degradation.

Chemical Composition & Mechanical Properties

Chemical Composition of ASTM A335 P91
Element Composition (%)
Carbon (C) 0.08–0.12
Manganese (Mn) 0.30–0.60
Phosphorus (P) ≤0.02
Sulfur (S) ≤0.01
Silicon (Si) 0.20–0.50
Chromium (Cr) 8.00–9.50
Molybdenum (Mo) 0.85–1.05
Vanadium (V) 0.18–0.25
Niobium (Nb) 0.06–0.10
Nitrogen (N) 0.03–0.07
Mechanical Properties of ASTM A335 P91
Property Value
Tensile Strength (MPa) 585 min
Yield Strength (MPa) 415 min
Elongation (%) 20 min
Hardness (HBW) ≤250
ASTM A335 P91 Type1 VS Type2
Grade UNS Designation Chemical Composition %
P91 Type 1 K91560 C Mn P S Si Ni Cr Mo
0.08-0.12 0.30-0.60 0.020 0.010 0.20-0.50 0.40 max 8.00-9.50 0.85-1.05
V N Al Cb Ti Zr Sn Sb
0.18-0.25 0.030-0.070 0.02 max 0.06-010 0.01 max 0.01 max _ _
P91 Type 2 K91560 C Mn P S Si Ni Cr Mo
0.08-0.12 0.30-0.50 0.020 0.005 0.20-0.40 0.40 max 8.00-9.50 0.85-1.05
V N Al Cb Ti Zr Sn Sb
0.18-0.25 0.035-0.070 0.02 max 0.06-0.10 0.01 max 0.01 max 0.010 max 0.003 max

ASTM A335 P91 Type 1 & Type 2 have subtle differences mainly in elements Mn, S, Si, N, Sn and Sb content, and Type 2 has stricter requirements on element content than Type 1. P91 type 1 and 2 shall have a hardness within the range of 190 to 250 [HBW] or 196 to 265 [HV] or 91 HRBW to 25 HRC.

Advantages of ASTM A335 P91 Alloy Steel

P91 (9Cr-1Mo-V-Nb) is a high-performance ferritic alloy steel designed for high-temperature service in power plants and petrochemical systems.

High Temperature Strength

Maintains mechanical performance up to 600°C, allowing reduced wall thickness in steam piping and headers.

Oxidation Resistance

Withstands aggressive thermal and chemical environments, supporting advanced boiler design.

Thermal Fatigue Life

Offers up to 10× longer fatigue life compared to conventional steels, reducing shutdowns and failures.

Microstructure Stability

Requires controlled heat treatment to maintain tempered martensitic structure and creep strength.

Alloy Composition

Chromium, molybdenum, vanadium, and niobium enhance strength, oxidation resistance, and weldability.

Weldability & Applications

Widely used in superheaters, reheaters, HRSGs, and headers with compatible welding consumables.

P91 alloy steel has become the industry standard for high-efficiency power plant systems. It delivers exceptional performance in demanding thermal environments and is essential for systems operating under high pressure and temperature conditions.

FAQ

ASTM A335 P91 is a seamless ferritic chrome moly alloy steel pipe used for high-temperature and anti-corrosion services. It contains 8.00–9.50% chromium and 0.85–1.05% molybdenum, with a minimum tensile strength of 415 MPa and yield strength of 205 MPa. It is commonly used in power plants, chemical plants, and other industrial facilities due to its excellent high-temperature strength and resistance to oxidation and corrosion.

ASTM A335/ASME SA335 Grade P91 is a ferritic alloy steel known for its high creep strength and resistance to thermal fatigue. Also referred to as 9Cr-1Mo steel, it is used in high-pressure, high-temperature environments such as boiler tubes, superheaters, and heat exchangers.

P91 Type 1 and Type 2 differ in chemical composition tolerances. Type 2 has stricter limits on elements like Mn, S, Si, N, Sn, and Sb. Both types share the same hardness range (190–250 HBW or 91 HRBW to 25 HRC) but are selected based on specific performance requirements.

P91 is a creep-strength-enhanced ferritic (CSEF) alloy steel made of 9% chromium and 1% molybdenum. It is designed to retain mechanical strength and stability at elevated temperatures, commonly used in high-temperature piping systems.

P91 (UNS K91560) is equivalent to the national standard 10Cr9Mo1VNb. It is a tempered martensitic heat-resistant steel containing elements like chromium, molybdenum, vanadium, and niobium, ensuring excellent thermal and mechanical performance.

P9 is a 9Cr-1Mo alloy steel suited for high-temperature service, while P91 includes additional elements like vanadium, niobium, and nitrogen to enhance creep resistance. P91 offers superior long-term performance under sustained high-temperature and pressure conditions.

P91 and T91 are essentially the same material. "P91" refers to seamless pipe under ASTM A335, while "T91" refers to tubing under ASTM A213. The difference lies in product form and specification, not the material itself.

P91 pipes come in various schedules and wall thicknesses ranging from 3 mm to 12 mm or more, depending on pipe diameter and pressure class. Custom thicknesses are also available to suit specific application requirements.

Industrial Applications

ASTM A335 chrome moly pipes are widely used in various industries due to their excellent mechanical properties and resistance to high temperatures.

Power Generation

Used in high-temperature and high-pressure boiler tubes, superheaters, and reheaters for efficient energy conversion.

Oil & Gas

Applied in refineries and petrochemical plants to transport high-temperature hydrocarbons.

Chemical Processing

Used in facilities handling corrosive and high-temperature fluids during various chemical reactions.

Nuclear Power

Employed in nuclear power plants for critical piping systems resistant to extreme heat and pressure.

Industrial Heating

Used in furnaces and heat exchangers due to excellent resistance to high temperature and thermal fatigue.

Steam Systems

Applied in high-pressure steam systems in industries like pulp and paper where thermal durability is essential.

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