Low Temperature Pipe

Low Temperature Pipe

Engineered For Resilience In Freezing Environments, Ideal For Cryogenic And Sub-zero Pipeline Systems.

Discover how low temperature carbon steel pipes (astm a333) deliver superior impact resistance, ductility, and reliability for cryogenic and subzero industrial systems.

Low-Temperature Carbon Steel Pipe is specially designed to perform in cryogenic and subzero conditions, offering outstanding impact toughness, ductility, and corrosion resistance. Conforming to ASTM A333 standards, this seamless carbon steel pipe is ideal for applications in LNG facilities, chemical plants, and power generation systems where temperatures drop below -50°C.

Cryogenic Performance

Maintains structural integrity and mechanical strength even at extreme cold temperatures down to -45°C (-50°F).

These ASTM A333 LTCS Seamless Pipes are produced through controlled rolling and heat treatment processes to ensure mechanical integrity at low temperatures. Available in multiple grades, such as Grade 1 and Grade 6, these pipes deliver reliable performance in structural, fluid, and gas transmission lines operating in subzero climates. The carbon-manganese alloy composition ensures high strength and resilience under thermal cycling and pressure variations.

LTCS Pipes are known for their weldability and ease of fabrication, making them suitable for complex boiler systems, heat exchangers, and refrigeration units. Pipes undergo strict quality checks, including Charpy V-Notch impact testing at -45°C, hydrostatic testing, and ultrasonic inspections to ensure compliance with industrial safety and durability standards.

Whether you're building a pipeline for arctic exploration or retrofitting industrial equipment in cold regions, Low Temperature Carbon Steel Pipes provide the mechanical robustness and thermal stability needed for long-term operation. Available in sizes from 1/2” to 48” and various wall thicknesses (SCH 40 to SCH 160), they can be custom-manufactured with plain, beveled, or threaded ends.

Combined with surface treatments such as galvanized coating, 3LPE, or epoxy painting, these pipes enhance longevity and corrosion resistance in harsh environments. Their high strength-to-weight ratio also minimizes structural load while maintaining safety under cryogenic conditions.

International Steel Grade Equivalents and Applications
Steel Grade Category GB (China) ASME(USA) DIN/EN (Euro) JIS (Japan) Application
Carbon steel 10 A106 St35.8 STB340 Economizer tube, Water wall tube, pipeline, header pipe, Petrochemical furnace tube, heat exchange tube
20 SA-106B St45.8 STB410
20G SA-106C P235GH STB510
20MnG SA-192 P265GH -
25MnG SA-210A1 - -
Q345B/C/D/E SA-210C - -
Mo steel 15MoG SA-209 T1 16Mo3 15Mo3 Water wall tube
Superheater tube
Reheater tube
20MoG SA-209 T1a - 16Mo3
- SA-209 T1b - -
Cr-Mo Steel 12Cr1MoG - 12Cr1MoV - Superheater tube
Reheater tube,
Pipeline, Header pipe, Petrochemical furnace tube, Heat exchange tube
Cr-Mo-V steel 12Cr2MoWVTiB - 14MoV63 -
Cr-Mo-Steel 12CrMoG T11/P11 10CrMo5-5 STB20
Cr-Mo-W Steel 15CrMoG T12/P12 12CrMo4-5 STB22
Cr-Mo Steel 12Cr2MoG T22/P22 10CrMo9-10 STB23 Superheater tube, Reheater tube, Main steam pipe, Pipleline, Header pip, Petrochemical furnace tube, Heat exchange tube
Cr-Mo-W steel 10Cr9Mo1VNbN T23/P23 7CrWVMoNb9-6 STB24
10Cr9MoW2VNbBN T24/P24 7CrMoVTIB10-10 STB25
12Cr1Mo T5/P5 X10CrMoVNb9-1 STB26
12Cr5Mol/NT T9/P9 X10CrWMoVNb9-2 -
12Cr9Mol/NT T91/P91 X11CrMo5+l/NT -
- T92/P92 X11CrMo9-1+l/NT -
Carbon steel 16MnDG A333-1 - STPL380 Tube & pipe for Low-temperature service
Ni steel 10MnDG SA-333-1 - STPL450
09DG A333-6 - -
- SA-333-6 - -
- A333-3 - -
- SA-333-3 - -
Austentic Stainless steel --- AP304 TP304H - --- Superheater tube, Reheater tube
- TP321 TP321H - -
- TP347 TP347H - -
- TP316 TP316H - -
- S30432 TP310HCbN - -

Sizes & Specifications

Size Range

Outer Diameter (O.D.): 1/4” Nominal to 24”
Wall Thickness: Schedule 10 through XXH (Extra Extra Heavy)

Pipe Specifications & Grades

Standards: ASTM A333 / ASME SA333
Grades Available: Grade 1, Grade 3, Grade 6
Welded Alternative: ASTM A671 EFW (for sizes over 24" O.D.)

Flanges & Forged Fittings

Standard: ASTM A350 / ASME SA350
Grades: LF2, LF3 (Low Temperature Service)

Buttweld Pipe Fittings

Standard: ASTM A420 / ASME SA420
Grades: WPL6, WPL3

Effect of Alloying Elements on Cryogenic Steels

Alloying elements significantly influence the performance of cryogenic steels, used from -10°C to -273°C, including aluminum-killed C-Mn steels (e.g., 06MnVTi), low-alloy ferritic steels (e.g., 0.5Ni), martensitic steels (e.g., 9Ni), and austenitic steels (e.g., 1Cr18Ni9Ti).

Mn (Manganese)

Enhances low-temperature toughness by forming a solid solution, expanding the austenite region, lowering transformation temperatures (A1 and A3), and refining ferrite and pearlite grains. An Mn/C ratio of 3 optimizes toughness and compensates for reduced mechanical properties due to lower carbon.

Ni (Nickel)

Reduces brittle transition temperature by 10°C per 1% increase (five times more effective than Mn), refines microstructure, and boosts toughness. Enables 9Ni steel for -196°C and 5Ni for -162°C to -196°C due to increased movable dislocations.

C (Carbon)

Increases brittle transition temperature and reduces weldability, limiting its content to below 0.2% in cryogenic steels.

P, S, Sn, Pb, Sb (Phosphorus, Sulfur, Tin, Lead, Antimony)

Harmful to toughness, these elements segregate at grain boundaries, lowering resistance and causing brittle cracks. Phosphorus boosts strength but increases brittleness, requiring strict limits.

O, H, N (Oxygen, Hydrogen, Nitrogen)

Raise brittle transition temperature. Aluminum-killed steels offer better toughness than silicon-killed steels, as silicon increases the transition temperature.

Summary

Alloying elements like Mn and Ni enhance toughness, while C, P, S, Sn, Pb, Sb, O, H, and N can degrade it by increasing brittle transition temperatures or promoting brittleness. Optimal composition is key for cryogenic performance.

What is Low temperature pipe?

ASTM A333

What is Low temperature pipe?

Low temperature pipe refers to pipes specifically designed to withstand and operate effectively in environments with low temperatures, typically below 0°C (32°F).

These pipes are often used in industries such as oil and gas, petrochemicals, and refrigeration, where fluids need to be transported or stored at low temperatures. They are constructed from materials that can maintain their mechanical properties and structural integrity even in extremely cold conditions, ensuring the safe and efficient transportation of fluids. Additionally, low temperature pipes are insulated to prevent heat transfer and maintain the desired temperature of the fluid being transported.

Compared with austenitic stainless steel and duplex stainless steel, there are many comprehensive advantages of ferrite alloy steels for low temperature service, such as higher strength, better rigidity and lower expansion coefificient. There is not only better stability but aslo higher heat transfer efficiency. Tube & pipe for low-temperature service can be widely used in low temperature engineering. ASTM/ASME A/SA-333 Grades allow for cold temperature service to minus 150 degrees F. Material is always provided in the normalized condition at a minimum and Charpy Impact tested to a specific temperature range to assure compliance with the required service temperature.

Key Features & Benefits

Low Temperature Service

Exceptional performance at temperatures down to -45°C with superior notch toughness and impact resistance.

Superior Toughness

Fine-grain structure with uniform carbide dispersion prevents brittle fracture in cryogenic conditions.

Cost-Effective

Economical alternative to exotic materials while providing reliable low-temperature performance.

Excellent Weldability

Good weldability using conventional processes with minimal post-weld heat treatment requirements.

Technical Specifications

Chemical Composition of ASTM A333 Alloy Pipe (% by Weight)
Grade C Si Mn P S Cr Ni Cu Mo V Al
Grade 1 ≤0.30 0.40–1.06 ≤0.025 ≤0.025
Grade 3 ≤0.19 0.18–0.37 0.31–0.64 ≤0.025 ≤0.025 3.18–3.82
Grade 4 ≤0.12 0.18–0.37 0.50–1.05 ≤0.025 ≤0.025 0.44–1.01 0.47–0.98 0.40–0.75 0.04–0.30
Grade 6 ≤0.30 ≥0.10 0.29–1.06 ≤0.025 ≤0.025
Grade 7 ≤0.19 0.13–0.32 ≤0.90 ≤0.025 ≤0.025 2.03–2.57
Grade 8 ≤0.13 0.13–0.32 ≤0.90 ≤0.025 ≤0.025 8.40–9.60
Grade 9 ≤0.20 0.40–1.06 ≤0.025 ≤0.025 1.60–2.24 0.75–1.25
Grade 10 ≤0.20 0.10–0.35 1.15–1.50 ≤0.03 ≤0.015 ≤0.15 ≤0.25 ≤0.015 ≤0.50 ≤0.12 ≤0.06
Grade 11 ≤0.10 ≤0.35 ≤0.6 ≤0.025 ≤0.025 ≤0.50 35.0–37.0 ≤0.50

* For Grade 1 and 6, each reduction of 0.01% C below 0.30% allows an increase of 0.05% Mn above 1.06%, up to 1.35%.
* For Grade 6, the columbium limit may increase to 0.05% (heat analysis) and 0.06% (product analysis).
* Generally, carbon equivalent (C.E.) = [C + Mn/6 + (Cr + Mo + V)/5 + (Ni + Cu)/15] shall not exceed 0.43% by heat analysis.

Mechanical Requirements of ASTM A333 Alloy Pipe
Grade Tensile Strength
(MPa)
Yield Point
(MPa)
Elongation Y (%) Elongation X (%)
ASTM A333 Grade 1 ≥380 ≥205 ≥35 ≥25
ASTM A333 Grade 3 ≥450 ≥240 ≥30 ≥20
ASTM A333 Grade 4 ≥415 ≥240 ≥30 ≥16.5
ASTM A333 Grade 6 ≥415 ≥240 ≥30 ≥16.5
ASTM A333 Grade 7 ≥450 ≥240 ≥30 ≥22
ASTM A333 Gr. 8 ≥690 ≥515 ≥22
ASTM A333 Grade 9 ≥435 ≥315 ≥28
ASTM A333 Grade 10 ≥550 ≥450 ≥22
ASTM A333 Grade 11 ≥450 ≥240 ≥18

* Elongation values are based on standard round 2-inch or 50 mm (or 4D) specimens.
* Elongation of Grade 11 applies to all wall thicknesses and small sizes tested in full section.

Production Specification Range of Low Temperature Pipe Products
No. Order No. O.D. (mm) W.T. (mm) Length (m)
1 A333 Gr.6 / A333 Gr.6 + X42NS 10–127 1–20 6–12.0
42–114.3 3.5–6 6–12.2
42–114.3 6–12 6–12.2
114.3–180 3.8–8 6–12.2
114.3–180 8–22 6–12.2
68–180 10–14 6–12.2
69–254 14–55 6–12.2
140–340 6–8 6–12.2
140–368 8–42 6–12.2
318–720 14–50 4–12.5
2 A333 Gr.6 + X52QS 42–114.3 3.5–12 6–12.2
114.3–180 3.8–22 6–12.2
68–254 10–40 6–12.2
140–368 6–40 6–12.2
318–720 14–40 4–12.5
140–368 6–25 6–12.2
318–720 14–25 4–12.5
3 16MnDG 10–127 1–20 6–12.0
42–114.3 3.5–12 6–12.2
114.3–180 3.8–22 6–12.2
68–254 10–55 6–12.2
140–368 6–42 6–12.2
318–720 14–120 4–12.5
Strike Temperature Conditions for ASTM A333 Grades
Grade Strike Test Temperature (℉) Strike Test Temperature (℃)
ASTM A333 Grade 1 -50 -45
ASTM A333 Grade 3 -150 -100
ASTM A333 Grade 4 -150 -100
ASTM A333 Grade 6 -50 -45
ASTM A333 Grade 7 -100 -75
ASTM A333 Grade 8 -320 -195
ASTM A333 Grade 9 -100 -75
ASTM A333 Grade 10 -75 -60
Dimensional Specifications
Parameter Range / Options
Size Range 1/4" to 42" O.D.
Wall Thickness SCH 10, SCH 20, SCH 40, SCH STD, SCH 80, SCH XS, SCH 160, SCH XXS
Length Options Single Random, Double Random, 20 ft, 40 ft
End Types Plain End, Beveled End
Manufacturing Seamless, Welded (no filler metal)
Temperature Performance Parameters
Grade Minimum Service Temperature Impact Test Temperature Typical Applications
Grade 1 -50°F (-45°C) -50°F General low-temperature service
Grade 3 -150°F (-101°C) -150°F Cryogenic applications with 3.5% Ni
Grade 6 -50°F (-45°C) -50°F Most common grade for power generation
Grade 8 -320°F (-196°C) -320°F Ultra-low temperature applications

Manufacturing Process

1
Steel Production & Composition Control

Precise control of chemical composition using electric arc furnaces with advanced ladle metallurgy techniques. Vacuum degassing reduces hydrogen content and eliminates inclusions.

2
Pipe Forming Operations

Seamless pipes manufactured using hot piercing and rolling. Welded pipes produced using ERW or SAW processes with strict welding parameter controls.

3
Heat Treatment

Controlled heat treatment including normalizing at 815°C (1500°F), quench and temper, or stress relief to achieve optimal microstructure and properties.

4
Quality Control & Testing

Comprehensive testing including chemical analysis, mechanical testing, Charpy V-notch impact testing, hydrostatic testing, and non-destructive examination.

FAQ

ASTM A333 is a standard specification for seamless and welded carbon and alloy steel pipes intended for low-temperature service. It ensures impact toughness at temperatures as low as -45°C (-49°F), suitable for cryogenic and sub-zero applications.

ASTM A333 includes grades 1, 3, 4, 6, 7, 8, 9, 10, and 11, each with specific chemical and mechanical properties to meet different application needs.

  • Tensile Strength: ≥ 415 MPa (60,000 psi)
  • Yield Strength: ≥ 240 MPa (35,000 psi)
  • Elongation: ≥ 30%
  • Impact Toughness: 13 J at -45°C (-49°F)

ASTM A333 pipes are used in:
  • Oil and gas transmission
  • LNG and cryogenic systems
  • Power plants
  • Chemical processing
  • Petrochemical industries

Pipes are produced using seamless or welding processes (without filler metal), followed by heat treatment to enhance toughness and structural properties.

Required tests include:
  • Tensile test
  • Impact test (Charpy V-notch)
  • Hydrostatic test
  • Non-destructive testing (e.g., ultrasonic or eddy current)

ASTM A333 pipes are available in sizes from 1/4" to 42" with wall thicknesses ranging from Schedule 10 to XXH (extra heavy).

ASTM A333 is used for low-temperature services with impact toughness requirements, while ASTM A106 is for high-temperature applications without such requirements.

ASTM A333 Grade 6 is a low-temperature carbon steel pipe designed for use in environments as cold as -45°C (-49°F), and it performs exceptionally well in cryogenic applications down to -452°F due to its superior notch toughness. ASTM A333 covers both seamless and welded pipes from 1/4″ to 24″ in outer diameter.

ASTM A106 Grade B is a high-temperature carbon steel seamless pipe commonly used in pressure systems and high-temperature services up to 430°C. While it offers high tensile strength and good oxidation resistance, it is not suitable for extremely low-temperature applications.

Key differences:
  • A333: Suitable for low-temperature/cryogenic service, with excellent toughness at sub-zero temperatures.
  • A106: Suitable for high-temperature service, but loses toughness in low-temperature conditions.
  • A333: Can be structural or pressure pipe; includes impact testing requirements.
  • A106: Typically used for pressure vessels, boilers, and piping systems without low-temp impact requirements.

Industrial Applications

Low Temperature Pipe is widely used in industries requiring excellent high-temperature, high-pressure, and corrosion-resistant performance.

Power Generation

Used in boilers, superheaters, and steam lines in thermal and nuclear power plants.

Petrochemical Industry

Ideal for hydrocarbon processing, ethylene cracking, and heat exchanger units.

Cryogenic Systems

Used in LNG pipelines, storage tanks, and vaporization equipment for cold media.

Heat Exchangers

Ensures excellent thermal conductivity and corrosion resistance in cyclic operations.

Oil & Gas Industry

Handles high-pressure oil and gas in extraction, refining, and transportation systems.

Chemical Processing

Resists acidic and corrosive environments in reactors, scrubbers, and distillation units.

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